¸å¼þȪԴ£º£º£ºÖÊÁÏ¿ÆÑ§Ó빤³ÌѧԺ ±à¼£º£º£ºÌ¸Ï£¡£¡¢¡¢¡¢Íõ¶¬Ã· ÉóºË£º£º£ºËïÒ«±ó ÔĶÁÁ¿£º£º£º
ngµç×ÓÓÎÏ·ÐÂÎÅÍøÑ¶£¨Í¨Ñ¶Ô±ÑîÑóÒ磩½üÄêÀ´£¬£¬ï®Àë×Óµç³ØÒÀ¸½Æä¸ßÄÜÁ¿Ãܶȼ°ÓÅÒìµÄÑ»·ÐÔÄÜÔö½øÁËÐÂÄÜÔ´µÄÓ¦ÓÃÓ뿪չ¡£¡£¿ÉÊÇ£¬£¬·ÇË®µç½âÖʵÄʹÓÃÁîÆä»·±£º£º£ºÍÇå¾²ÎÊÌâÄÑÒÔսʤ¡£¡£×î½ü²½ÈëÈËÃÇÊÓÒ°µÄÐÂÐÍˮϵп½ðÊôµç³Ø²»µ«Çå¾²·çÏÕÏÔÖø½µµÍ£¬£¬¸ßƷòµÄÐ¿ÔªËØÓëÇáÓ¯µÄ×é×°ÇéÐÎÒ²´ó´óïÔÌÁËµç³ØµÄÖÊÁϱ¾Ç®Ó빤ÒÕ±¾Ç®¡£¡£Ð¿½ðÊôµç³Ø»¹¾ßÓнϸߵÄÀíÂÛÈÝÁ¿ºÍµÍÑõ»¯»¹Ôµç룬£¬Òò´Ë³ÉΪÏÖÔÚ±¸ÊܹØ×¢µÄ´¢ÄÜµç³Ø¡£¡£
³¬·Ö×Ó»¯ºÏÎïÊÇ»ùÓÚ·Ö×Ó¼äµÄ·Ç¹²¼ÛÈõ¼üµÞºÏ£¨º¬Åäλ¼ü¡¢¡¢¡¢Çâ¼ü¡¢¡¢¡¢Â±¼ü¡¢¡¢¡¢¦Ð-¦ÐȺ¼¯¡¢¡¢¡¢Ç×ÊèË®×÷Óõȣ©¶øÐγɵ쬣¬¾ßÓÐÌØ¶¨½á¹¹ºÍ¹¦Ð§µÄ·Ö×Ó¾ÛÕûÌå¡£¡£ngµç×ÓÓÎÏ·ÖÊÁÏ¿ÆÑ§Ó빤³ÌѧԺÑîÑóÒç½ÌÊÚ¿ÎÌâ×é»ùÓÚ¶Ô³¬·Ö×ÓÍøÂç½á¹¹¡¢¡¢¡¢·Ö×Ó¼äÈõ¼üµÞÏàÖúÓÃËùÕ¹ÏÖµÄÓÅÁ¼½á¹¹¿ÉÄæÐÔ/×ÔÐÞ¸´¹¦Ð§¡¢¡¢¡¢µçºÉ´«ÊäÄÜÁ¦µÈÌØÕ÷µÄÊìϤ£¬£¬ÂÊÏÈÌá³ö½«ÆäÓ¦ÓÃÓÚÐÂÐ͵缫ÖÊÁϵÄÉè¼ÆÓëÖÆ±¸¡£¡£Ï£Íûͨ¹ý¶À±Ùõè¾¶£¬£¬Ì½Ë÷Ñо¿È«Ð¸ßЧµÄ³¬·Ö×ӵ缫£¬£¬ÔÚ´óÈÝÁ¿¡¢¡¢¡¢¿ìËÙ´¢ÄÜ·½ÃæÈ¡µÃÍ»ÆÆ£¬£¬Îª¹¹½¨ÐÂÐÍ´¢ÄÜϵͳÌṩеÄ˼Ð÷¡£¡£
ÓÃÓÚ¸ßÐÔÄÜˮϵ˫Àë×Óµç³ØµÄ¶þÎ¬ß²ßøÅä볬·Ö×ÓÍøÂçÕý¼«
ͨ¹ý¼òÆÓÈܼÁÈÈ·¨ÖƱ¸ÁËÒ»ÖÖÃûΪ Zn-TCPP µÄ¶þÎ¬ß²ßø-Åä볬·Ö×ÓÍø¸ñ£¨CSN£©µÄµâ-Ë«Àë×Óµç³Ø£¨DIBs£©Õý¼«£¬£¬²¢ÓëZnSO4 + KIË®ÐÔµç½âÖʺÍп½ðÊôÑô¼«Ò»Æð×é×°³Éˮϵ˫Àë×Óµç³Ø£¬£¬Õ¹Ê¾³öÓÅÒìµÄµç»¯Ñ§ÐÔÄÜ¡£¡£×÷Õß̫ͨ¹ý×Ó¹ìÔÀíÂÛ˵Ã÷Îú I3? ºÍ߲߸µªÖ®¼äµÄµçºÉ×ªÒÆÏ໥×÷Ó㬣¬²¢Ê¹ÓÃ×ÏÍâ¿É¼ûÎüÊÕ¹âÆ×ºÍÀÂü¹âÆ×֤ʵÁËÕâÒ»µã£¬£¬±ðµÄÃܶȷºº¯ÀíÂÛ£¨DFT£©ÅÌËãÒ²¶Ô´Ë¼ÓÒÔÑéÖ¤¡£¡£ ͬʱ£¬£¬ÅÌËãÁ÷Ì嶯Á¦Ñ§£¨CFD£©·ÂÕæÅÌËãÅú×¢ Zn-TCPP µÄ¶þά²ã×´ÍøÂç½á¹¹¸üÓÐÀûÓÚI3?µÄÉøÍ¸ºÍ궨¡£¡£ÂÛÎĵÚÒ»×÷Õߣº£º£º20¼¶²©Ê¿Ñо¿ÉúÌ·Ô¶Ãú£»Í¨Ñ¶×÷Õߣº£º£ºÑîÑóÒ磻µÚÒ»µ¥Î»£º£º£ºngµç×ÓÓÎÏ·ÖÊÁÏ¿ÆÑ§Ó빤³ÌѧԺ£¨Angew. Chem. Int. Ed. 2023, 62, e202217744£©¡£¡£

ͼ 1. £¨a£©Zn-I DIB ʾÒâͼ¡£¡££¨b£©Zn-TCPP µÄ¾§Ìå½á¹¹¡£¡££¨c£©Zn-TCPP ÔÚ 5 A g?1 ÏÂʹÓòî±ðµç½âÖʵÄÑ»·ÐÔÄÜ¡£¡££¨d£©Zn-TCPP µÄ XRD ͼÆ×¡£¡£

ͼ 2. £¨a£©I3? µÄ·Ö×Ó¹ìµÀͼ¡£¡££¨b£©TCPP ºÍ Zn-TCPP µÄ߲߸µª·Ö×Ó¹ìµÀ½á¹¹¡£¡££¨c£©TCPP ºÍ Zn-TCPP µÄ EDESP µÈÖµÃæÍ¼¡£¡££¨d£©TCPP µÄ ESP µÈÖµÃæÍ¼¡£¡£

ͼ 3. £¨a£©Zn-TCPP ºÍ TCPP µÄ HOMO ºÍ LUMOµÈÖµÃæÍ¼¡£¡££¨b£©Zn-TCPP ºÍ TCPP Õý¼«µÄ EIS ÇúÏß¡£¡£I3? ÔÚ£¨c£©Zn-TCPPºÍ£¨d£©H2OÉϵÄÎü¸½¹¹ÐͺÍÎü¸½ÄÜ¡£¡££¨e£©H2OÔÚZn-TCPPÉϵÄÎü¸½¹¹ÐͺÍÎü¸½ÄÜ¡£¡££¨f£©Zn-TCPP/I3? µÄEDDµÈÖµÃæÍ¼ºÍ£¨g£©Zn-TCPP/ I3? µÄIGMHµÈÖµÃæÍ¼¡£¡££¨h£©Zn-TCPP/ I3? µÄIRIµÄµÈÖµÃæÍ¼¡£¡££¨i£©Zn-TCPP/I3? µÄ PDOS ºÍ OPDOSÇúÏß¡£¡£
Åä볬·Ö×ÓÍø¸ñÊèË®½çÃæÊµÏÖ³¤Ñ»·ÎÞÖ¦¾§Ð¿½ðÊôµç³Ø
ʹÓÃÇáÓ¯µÄʪ»¯Ñ§·¨¹¹½¨Á˾ßÓÐϸÃÜȺ¼¯µÄ Zn-TSA (TSA = thiosalicylate) Åä볬·Ö×ÓÍø¸ñ£¨CSN£©µÄп¸º¼«½çÃæ¡£¡£ÊèË®ÐÔ Zn-TSA Íø¸ñ¿ÉÒÔ×èµ²ÈܼÁ»¯Ë®²¢½¨Éè¹Ì̬À©É¢ÆÁÕÏ£¬£¬Ê¹½çÃæ Zn2+ ÂþÑÜÓÅÒ죬£¬´Ó¶øÒÖÖÆ¸º¼«ÉÏÎöÇâºÍп֦¾§µÄÉú³¤¡£¡£Í¬Ê±£¬£¬Zn-TSAÍø¸ñÓÕµ¼ÐγÉÓɶàÖÖÎÞ»ú-Óлú»¯ºÏÎï×é³ÉµÄÔȳÆÎȹ̵ĹÌÌåµç½âÖʽçÃæ¡£¡£ÕâÖÖ¸üÖÂÃܵĽṹ¿ÉÒÔ˳ӦºÍ×ÔÎÒÐÞ¸´¼°Öظ´Ìå»ýת±äµ¼ÖµÄÑô¼«½çÃæÁÑÎÆ/½µ½â£¬£¬²¢ÒÖÖÆÓк¦¸±²úÆ· Znx(OTF?)y(OH)2x-y¡¤nH2O µÄ±¬·¢¡£¡£ÕâÖÖºÏÀíÖÆÔìµÄ¸º¼«/µç½âÖʽçÃæ½øÒ»²½¸³Óè×é×°µÄ¶Ô³Æµç³ØÁè¼Ý 2000 СʱµÄÓÅÒìµç¶Æ/°þÀëÎȹÌÐÔ£¬£¬¶ø²»»áÐγÉÖ¦¾§£¨ÔÚ 1 mA cm-2 ºÍ 1 mAh cm-2 Ï£©¡£¡£±ðµÄ£¬£¬ÕâÖÖп¸º¼«ÔÚ Zn-MoS2 ºÍ Zn-V2O5 È«µç³ØÖоßÓÐÏÖʵӦÓüÛÖµ¡£¡£ÂÛÎĵÚÒ»×÷Õߣº£º£º19¼¶²©Ê¿Ñо¿ÉúÌÕÔöÈÊ£»ÅäºÏͨѶ×÷Õߣº£º£ºÓÚÃ÷ºÆ£¨Technische Universit?t Dresden£©¡¢¡¢¡¢ÑîÑóÒ磻µÚÒ»µ¥Î»£º£º£ºngµç×ÓÓÎÏ·ÖÊÁÏ¿ÆÑ§Ó빤³ÌѧԺ£¨Small 2022, 18, 2107971£©¡£¡£

ͼ 4.£¨a£©ÂãпÍâòµÄп֦¾§Éú³¤»úÖÆÊ¾Òâͼ¡£¡££¨b£©Zn-TSA@Zn¸º¼«ÉϵÄSEIÐγɻúÖÆ¡£¡££¨c£©Zn-TSA@Znµç¼«µÄºá½ØÃæºÍ£¨d£©ÍâòSEMͼÏñ¡£¡££¨e£©Zn-TSA µÄ XRD ͼ¡£¡££¨f£©Zn-TSA ½á¹¹µÄ¶àÃæÌåÐÎò£¬£¬Õ¹Ê¾ÁËTSAÖе¥¸öZn(II)Èý½Ç˫׶ƬµÄÊèÉ¢³Ì¶È¡£¡££¨g£©TGÇúÏߺͣ¨h£©Zn-TSAµÄµªÎü¸½/ÍѸ½µÈÎÂÏßͼ¡£¡£

ͼ 5. Ôλµç×Ó¹âѧÏÔ΢¾µÍ¼ÏñÏÔʾÁË£¨a£©Âãпµç¼«ºÍ£¨b£©¶Ô³ÆÍ¸Ã÷µç³ØÖÐZn-TSA@Znµç¼«µÄǰÍâò£¬£¬ÒÔ¼°µç¶Æ/°þÀëÖÜÆÚµÄ»®¶¨ÃüÄ¿£¬£¬ÒÔ¼°ÏìÓ¦µÄºãµçÁ÷ÇúÏߣº£º£º£¨c£©Zn||ZnºÍ£¨d£©Zn-TSA@Zn||Zn-TSA@Zn¶Ô³Æµç³Ø¡£¡££¨e£©Âãп²ºÍZn-TSA@Znµç¼«ÔÚ3 M Zn(OTF)2Ë®ÈÜÒºÖе͝µçλ¼«»¯ÇúÏß¡£¡££¨f£©ÂãпºÍÍ¿²ãпÔÚ-150 mV¹ýµçλϵļÆÊ±µçÁ÷ͼ£¨CAs£©¡£¡££¨g£©Cu||ZnºÍCu||Zn-TSA@Znµç³ØÔÚ1 mA cm-2ºÍÈÝÁ¿Îª1 mAh cm-2ʱ¶ÆÐ¿/°þÀëµÄ¿âÂ×ЧÂÊ¡£¡££¨h£©Cu||ZnÂãµç³ØÔÚµÚ 1¡¢¡¢¡¢5ºÍ20´ÎÑ»·Ê±µÄµçѹÇúÏߣ¬£¬ÒÔ¼°£¨i£©Cu||Zn-TSA@Zn µç³ØÔÚµÚ1¡¢¡¢¡¢5¡¢¡¢¡¢20¡¢¡¢¡¢100¡¢¡¢¡¢300ºÍ500´ÎÑ»·Ê±µÄµçѹÇúÏß¡£¡£
ˮϵ˫Àë×Óµç³ØµÄÅä볬·Ö×ÓÍøÂçÕý¼«ÒÔµçºÉ×ªÒÆÏ໥×÷ÓÃ궨 I3¨C
µâÔڵ绯ѧ´¢ÄÜÁìÓòÓÐ×ÅÁÉÀ«µÄÓ¦ÓÃÔ¶¾°¡£¡£È»¶ø£¬£¬µâÈýÀë×Ó£¨I3¨C£©µÄ¸ßÏûÈÚ¶ÈÑÏÖØ×è°ÁË×Åʵ¼ÊÓ¦Ó㬣¬¶Ô I3¨C 궨»úÀíÑо¿µÄȱʧҲÑÏÖØ×è°ÁËÏȽøµâµç³ØÕý¼«ÖÊÁϵĿª·¢¡£¡£¿ÎÌâ×éÓ¦ÓÃË®ÈÈ·¨ÖƱ¸Á˾ßÓÐÈýÎ¬ÍøÂç½á¹¹µÄÅä볬·Ö×ÓZn-CSN£¬£¬½«ÆäÓÃ×÷Ë«Àë×Óµç³Ø£¨DIBs£© Õý¼«¡£¡£Í¨¹ý½« KI ÒýÈë¹Å°åµÄˮϵ ZnSO4 µç½âÒº£¬£¬»ñµÃÁ˺¬ÓÐ I3¨C/I¨C ºÍ Zn2+/Zn0 Ñõ»¯»¹Ôµç¶ÔµÄˮϵ DIB µç½âÒº£¬£¬ÆäÈÝÁ¿ÏÔ×ÅÔöÌí£¬£¬ÊµÏÖÁË 1.2 V µÄ¸ßµçѹ£¬£¬5 A g¨C1 ÏÂ207 mAh g¨C1 µÄ¸ß·Åµç±ÈÈÝÁ¿ºÍ 233 Wh kg¨C1 µÄ¸ßÄÜÁ¿Ãܶȣ¬£¬²¢ÇÒÔÚ5000 ´ÎÑ»·ºó±ÈÈÝÁ¿ÈÔÈ»¼á³ÖΪ 212 mAh g¨C1£¬£¬¿âÂ×ЧÂʸߴï 97%¡£¡£»ùÓÚ·Ö×Ó¹ìÔÀíÂÛÑо¿ÁËÓµÓЦÒ*·´¼ü¿Õ¹ìµÀµÄI3¨Cµç×ÓÊÜÌåÓë´øÓй¶Եç×ÓµÄà×वªµç×Ó¹©ÌåÖ®¼äµÄµçºÉ×ªÒÆÏ໥×÷Óᣡ£Ê¹ÓÃ×ÏÍâ-¿É¼ûÎüÊÕ¹âÆ×£¬£¬Ì½Ë÷ÁËà×वªÎü¸½ I3¨C ºó±¬·¢µÄµçºÉ×ªÒÆ¹âÆ×£¬£¬Ö¤ÊµÁ˵çºÉ×ªÒÆÏ໥×÷Óõı¬·¢¡£¡£»¹Ê¹ÓÃÀÂü¹âÆ×À´Ö¤Êµà×वªºÍ I3¨C Ö®¼äµÄ¼üºÏ¡£¡£±ðµÄ£¬£¬DFT ÅÌËã±»ÓÃÓÚÑо¿à×वª¶Ô I3¨C µÄÎü¸½¡£¡£ÂÛÎĵÚÒ»×÷Õߣº£º£º20¼¶²©Ê¿Ñо¿ÉúÌ·Ô¶Ãú£»Í¨Ñ¶×÷Õߣº£º£ºÑîÑóÒ磻µÚÒ»µ¥Î»£º£º£ºngµç×ÓÓÎÏ·ÖÊÁÏ¿ÆÑ§Ó빤³ÌѧԺ£¨ACS Appl. Mater. Interfaces 2022, 14, 47716¨C47724£©

ͼ 6.£¨a£©Zn?I DIB »úÖÆµÄʾÒâͼ¡£¡££¨b£©Zn-PymSH µÄ XRD ͼ¡£¡££¨c£©Zn-PymSH ÖÐпÔ×ÓµÄÅäλ²ã¡£¡££¨d£©Zn-PymSH µÄ 3D ÍøÂç½á¹¹¡£¡£

ͼ 7.£¨a£©I3? ÔÚ Zn-PymSH µÄà×वªÉϵÄÎü¸½¹¹ÐͺÍÎü¸½ÄÜ¡£¡££¨b£©Îü¸½ÔÚ Zn-PymSH/I3? µÄ EDDµÈÖµÃæÍ¼¡£¡££¨c£©Zn-PymSH/I3?µÄ PDOS ºÍ OPDOSÇúÏß¡£¡£
ÔλÉú³¤µÄÇ×Ë®ÐÔÅä볬·Ö×ÓÍø¸ñʵÏÖп½ðÊôµç³ØµÄÎȹ̳¬³¤Ñ»·ÊÙÃü
ʹÓÃÔλÉú³¤·¨ÖƱ¸¶þÁò´úË®ÑîËáп(Zn-DTA)Åä볬·Ö×Ó(CSNs)Í¿²ãµÄÐÂÐÍпÑô¼«¡£¡£Zn-DTA±£»¤²ãµÄһάÁ´×´¶Ñµþ½á¹¹¾ßÓнϸßÄÜÀÝ£¬£¬ÒÖÖÆÁËпÀë×ÓÔڵ缫ÍâòµÄ¶þάÀ©É¢¡£¡£ÅäÎ»ÍøÂçÌṩµÄ¸»ºñµÄ»îÐÔλµãÒ²ÓÐÓõØÔö½øÁËпÀë×ӵĿìËÙǨá㣬£¬¸ÄÉÆÁ˵绯ѧ¶¯Á¦ÐÔÄÜ¡£¡£Ð§¹ûÅú×¢£¬£¬Ê¹ÓÃZn-DTA@Znµç¼«×é×°µÄ¶Ô³Æµç³ØÔÚ1 mA cm?2ÏÂÊÂÇé2000 hÒÔÉÏ¡£¡£Ð¿Íµç³ØÔËÐÐ1000´Î£¬£¬ÇÒÆ½¾ù¿âÂØÐ§ÂÊΪ99.07%¡£¡£±ðµÄ£¬£¬Zn//V2O5È«µç³ØÌåÏÖ³öÓÅÒìµÄ±¶ÂÊÐÔÄÜ£¬£¬ÔÚ2 A g?1Ï¿ÉÑ»·1500´Î¡£¡£×îºó£¬£¬»¹×é×°ÁË×¼¹Ì̬µç³Ø£¬£¬Í¨¹ý1000СʱÒÔÉϵÄÊÙÃüչʾÁË×Åʵ¼ÊÓ¦ÓõĿÉÄÜÐÔ¡£¡£ÕâÖÖÇáÓ¯¸ßЧµÄÔλÉú³¤Í¿²ãʹˮϵп½ðÊôµç³ØµÄ¹æÄ£»¯Ó¦ÓÃÕ¹ÏÖ³öÓÕÈ˵ÄÔ¶¾°¡£¡£ÅäºÏµÚÒ»×÷Õߣº£º£º20¼¶Ë¶Ê¿ÉúÍõ°²¶¦£¬£¬19¼¶²©Ê¿Ñо¿ÉúÌÕÔöÈÊ£»Í¨Ñ¶×÷Õߣº£º£ºÑîÑóÒ磻µÚÒ»µ¥Î»£º£º£ºngµç×ÓÓÎÏ·ÖÊÁÏ¿ÆÑ§Ó빤³ÌѧԺ£¨J. Power Sources 2023, 555, 232370£©

ͼ 8. пÀë×ÓÔÚÑô¼«ÍâòµÄ³Á»ýÐÐΪʾÒâͼ:£¨a£©Ð¿ÔÚÂãпÑô¼«ÉϵIJ»ÔȳƳÁ»ýµ¼Ö´ó×ÚȺ¼¯Ö¦¾§£¬£¬Åãͬ¸±²úÆ·ºÍ¸±·´Ó³±¬·¢µÄÆøÌå¡£¡££¨b£©Zn-DTA@ZnÑô¼«¾ßÓÐÓÅÁ¼µÄп³Á»ýÐÐΪµ÷ÀíÄÜÁ¦£¬£¬Ê¹»ñµÃµÄÑô¼«ÍâòÔȳơ£¡£

ͼ 9.£¨a£©Zn-DTA²ãÔλºÏ³É¹¤ÒÕʾÒâͼ¡£¡££¨b£©Zn-DTA½á¹¹Ê¾Òâͼ¡£¡££¨c£©Zn-DTAµÄXRDͼÆ×(²Î¿¼Í¼Æ×ºÍÏÖʵ²úƷͼÆ×)¡£¡££¨d£©ÔʼZn-DTAÑô¼«½ØÃæSEMͼÏñ¡£¡££¨e£©Zn-DTA@Znµç¼«µÄSEMͼÏñºÍÄÜÁ¿É«É¢¹âÆ×£¨EDS£©Ó³É䣬£¬ÏÔʾÁËC¡¢¡¢¡¢O¡¢¡¢¡¢SºÍZnµÄÔªËØÂþÑÜ¡£¡££¨f£©ÉÏÊöZn-DTA·ÛÄ©µÄÈÈÖØ£¨TGA£©ÇúÏß¡£¡££¨g£©Zn-DTA·ÛÄ©µÄÎü¸½/½âÎüÇúÏß¡£¡£È¥Àë×ÓË®ÔÚ£¨h£©Zn-DTA@ZnºÍ£¨i£©Âãпµç¼«ÉϵĽӴ¥½ÇÕÉÁ¿¡£¡£
ÂÛÎÄÁ´½Ó£º£º£º
Angew. Chem. Int. Ed. 2023, 62, e202217744. https://doi.org/10.1002/anie.202217744
Small 2022, 18, 2107971. https://doi.org/10.1002/smll.202107971
ACS Appl. Mater. Interfaces 2022, 14, 47716¨C47724. https://doi.org/10.1021/acsami.2c12962
J. Power Sources 2023, 555, 232370. https://doi.org/10.1016/j.jpowsour.2022.232370