ngµç×ÓÓÎÏ·ÐÂÎÅÍøѶ£¨Í¨Ñ¶Ô±Áõ¿¡Á¼£©ÔÚÈÈ¡¢¹â»òѹÁ¦µÈÍâ½çÈŶ¯Ï£¬£¬£¬´ÅÐÔ·Ö×ÓÖÊÁϳÊÏÖ³ö¸»ºñÇҿɿصĴ̼¤ÏìÓ¦ÐÐΪ¡£ÊµÏÖ¶Ô·Ö×ӽṹ¡¢µç×ÓÄܼ¶¼°ºê¹Û´ÅµçÐÔÄܵĵ÷¿ØÓëʹÓ㬣¬£¬ÔÚ´ÅÓ°ÏóÖÊÁÏ¡¢×ÔÐýµç×ÓѧÆ÷¼þºÍ·Ö×Ó¿ª¹ØÖоßÓÐÁÉÀ«µÄÓ¦ÓÃÔ¶¾°¡£½«È˹¤·Ö×Ó»úеµÄ¿´·¨ÒýÈëµ½´ÅÐÔ·Ö×ÓÖÊÁϵÄÉè¼ÆÖУ¬£¬£¬ÓÐÍûÔÚ·Ö×ÓˮƽÉϾ«×¼²Ù¿Ø¾ßÓд̼¤ÏìÓ¦ÌØÕ÷µÄ´ÅµçÐÔÄÜ¡£
ͼ1 ½ª-Ì©ÀÕÖáµÄ¿ÉÄæת»»ºÍ¹ÚÃÑ¡°×ª×Ó¡±µÄÈȸ¨Öúת¶¯
¹ÚÃÑÓÉÓÚÆä½á¹¹ÎÞа£¬£¬£¬¿É³äµ±ÓÐÐò-ÎÞÐòÐÍÏà±äÀú³ÌÖзÖ×ÓÂí´ïµÄ¡°×ª×Ó¡±£¬£¬£¬±»ÆÕ±éÓÃÓÚÐÞ½¨È˹¤·Ö×Ó»úе¼°½á¹¹Ïà±äÅäºÏÎï¡£×î½ü£¬£¬£¬·Ö×Ó´ÅÌåÑо¿ÍŶÓͨ¹ýÑ¡ÓÃ18-¹ÚÃÑ-6ºÍ¾ßÓнª-Ì©ÀÕЧӦµÄCo(II)Àë×Ó£¬£¬£¬ÇÉÃîºÏ³ÉÁËÒ»Àý¾ßÓС°Rc¡¤¡¤¡¤Rw?S?Rw¡¤¡¤¡¤Rc¡±Ðͳ¬·Ö×ӽṹµÄ´ÅÐÔÅäºÏÎÆäÖÐRcºÍRw»®·ÖÖ¸´ú¹ÚÃѺÍË®·Ö×Ó¡°×ª×Ó¡±£¬£¬£¬SÖ¸´úCo(II)¡°¶¨×Ó¡±£©¡£ÉÏÊö´ÅÐÔ·Ö×Ó¹ÌÌåÔÚÊÒÎÂÖÜΧ±¬·¢¿ÉÄæÒ»¼¶Ïà±ä£¬£¬£¬¾§Ìå½á¹¹ÉÏÖ÷ÒªÌåÏÖ³ö½ª-Ì©ÀÕÖáµÄ¿ÉÄæת»»ÒÔ¼°18-¹ÚÃÑ-6¡°×ª×Ó¡±µÄÈȸ¨Öúת¶¯£¨Í¼1£©£¬£¬£¬¿ÉÍƶϸßÎÂʱת¶¯µÄ¹ÚÃÑ̫ͨ¹ý×Ó¼äÇâ¼üÀ¶¯Åäλˮ·Ö×Ó£¬£¬£¬´Ó¶ø´¥·¢ÁË·Ö×ӽṹµÄ¶¯Ì¬×ª±ä¡£
ͼ2 ´Å¸÷ÏòÒìÐÔÓë´Å½éµçЧӦµÄÈȸ¨Öúµ÷¿Ø
µ¥¾§½Ç·Ö±æ´ÅÐÔ²âÊÔÅú×¢£¬£¬£¬´ÅÐÔ·Ö×ӵĴŸ÷ÏòÒìÐÔÔÚÏà±äÇ°ºó±¬·¢ÁËÏÔÖøת±ä£º£º£º´ÓµÍÎÂÏàת±äÖÁ¸ßÎÂÏàʱ£¬£¬£¬Ò×´Å»¯ÖáÍù¼ü³¤Ëõ¶ÌµÄN4Åäλ³àµÀƽÃæת¶¯ÁË14.6¡ã£¬£¬£¬¶øÄÑ´Å»¯ÖáÍù¼ü³¤ÔöÌíµÄCo-OÖáÏòÅäλ¼üת¶¯ÁË14.1¡ã¡£ÓÉÓÚÏà±äÇ°ºó·Ö×ӽṹÓë´Å¸÷ÏòÒìÐÔ¾ù·ºÆðÏÔ×Åת±ä£¬£¬£¬Òò´ËÆä×ÔÐý-¾§¸ñÏ໥×÷ÓÃÒ²»á±¬·¢¸Ä±ä¡£µ¥¾§´Å½éµç²âÊÔÏÔʾ£¬£¬£¬¸ßÎÂÏàÏÕЩûÓÐÊӲ쵽´Å½éµçЧӦ£¬£¬£¬¶øµÍÎÂÏàÔòÌåÏÖ³öÏÔÖøµÄ¸º´Å½éµçЧӦ£¬£¬£¬Åú×¢Æä¸ßÎÂÏà¿ÉÄܱ£´æ¸üÇ¿µÄ×ÔÐý-¾§¸ñÏ໥×÷Óá£
¸ÃÊÂÇ龫׼Éè¼ÆÓëºÏ³ÉÁËÒ»ÀýÓÐÐò-ÎÞÐòÐÍCo(II)Ïà±äÅäºÏÎ£¬£¬½ª-Ì©ÀÕÖáºÍ¹ÚÃÑ¡°×ª×Ó¡±µÄÈȸ¨Öú¶¯Ì¬×ª±äÒý·¢ÁËÅäºÏÎï´ÅµçÐÔ×ӵĿÉÄæת»»£¬£¬£¬µÚÒ»´ÎΪÏà±äÐÍ·Ö×Ó´ÅÐÔ×ÓÁϵĵ¥¾§´Å¸÷ÏòÒìÐÔ¼°´Å½éµçЧӦµÄÐͬµ÷¿ØÌṩÁ˹淶¡£
¸ÃÑо¿ÂÛÎÄÒÔ¡°Reversible Switchability of Magnetic Anisotropy and Magnetodielectric Effect Induced by Intermolecular Motion¡±ÎªÌ⣬£¬£¬½ÒÏþÔÚ¡¶µÂ¹úÓ¦Óû¯Ñ§¡·£¨Angewandte Chemie International Edition£©¡£ngµç×ÓÓÎÏ·»¯Ñ§Ñ§ÔºÎª¸ÃЧ¹ûµÄµÚÒ»Íê³Éµ¥Î»£¬£¬£¬²©Ê¿Ñо¿Éú¶ÅɼéªÎªÂÛÎĵÚÒ»×÷Õߣ¬£¬£¬Áõ¿¡Á¼½ÌÊÚºÍÖØÇì´óѧËïÑô½ÌÊÚΪÅäºÏͨѶ×÷Õß¡£¸ÃÑо¿»ñµÃÁËͯÃ÷Á¼½ÌÊڵĴóÁ¦Ö§³Ö£¬£¬£¬²¢»ñµÃ¹ú¼ÒÖصãÑз¢ÍýÏë¡¢¹ú¼Ò×ÔÈ»¿Æѧ»ù½ðÖصãÏîÄ¿¡¢¹ú¼Ò×ÔÈ»¿Æѧ»ù½ðÃæÉÏÏîÄ¿¡¢¹ã¶«Ê¡¡°Öé½È˲ÅÍýÏ롱±¾ÍÁÁ¢Òì¿ÆÑÐÍŶÓÏîÄ¿µÄÖ§³Ö¡£
ÂÛÎÄÁ´½Ó£º£º£ºhttps://doi.org/10.1002/anie.202204700
µØµã:¹ãÖÝÊÐиÛÎ÷·135ºÅ Óʱà:510275
µç»°: 020-84112828
ngµç×ÓÓÎÏ·°æȨËùÓÐ COPYRIGHT?1999-2022 , SUN YAT-SEN UNIVERSITY