ngµç×ÓÓÎÏ·

05

¿ÆÑÐÏ£Íû

Íô¾ý¿ÎÌâ×飺£º£ºÊ¹ÓÃÊÖÐÔ·¼ÌþÅäÌåʵÏÖ²î³Ø³Æ´ß»¯Ì¼Çâ»î»¯

¸å¼þȪԴ£º£º£º»¯Ñ§Ñ§Ôº ±à¼­£º£º£ºÖ£Áú·É¡¢¡¢¡¢Íõ¶¬Ã· ÔĶÁÁ¿£º£º£º

ngµç×ÓÓÎÏ·ÐÂÎÅÍøÑ¶£¨Í¨Ñ¶Ô±Íô¾ý£©²î³Ø³ÆÌ¼Çâ»î»¯Ñо¿ÊÇÓлú»¯Ñ§µÄÇ°ÑØÑо¿Æ«Ïò£¬¾ßÓÐÖ÷Òª¿ÆÑ§ÒâÒåºÍÊÊÓüÛÖµ¡£¡£ngµç×ÓÓÎÏ·»¯Ñ§Ñ§ÔºÍô¾ý¿ÎÌâ×éÒ»Ö±ÖÂÁ¦ÓÚ²î³Ø³ÆÌ¼Çâ»î»¯Ñо¿£¬ÔÚÊÖÐÔ»·Îì¶þÏ©îî(III)£¨CpRhIII£©´ß»¯µÄ²î³Ø³ÆÌ¼Çâ»î»¯·½ÃæÈ¡µÃÁËϵÁÐЧ¹û¡£¡£ÀýÈ磬ËûÃÇʹÓÃÁªÝÁºÍÂÝ»·¹Ç¼ÜµÄÊÖÐÔCpRhIIIʵÏÖÁ˶à¸ö²î³Ø³ÆÌ¼Çâ¼ü»î»¯·´Ó³£¨Angew. Chem. Int. Ed. 2019, 58, 6732£»£»Angew. Chem. Int. Ed. 2018, 57, 4048£»£»Org. Lett. 2020, 22, 3586£»£»Org. Lett. 2020, 22, 3219£©¡£¡£ÁíÍ⣬ËûÃÇ»¹¿ª·¢ÁËÈýÖÖÊÖÐÔCpÅäÌå»òCpM´ß»¯¼Á£¬°üÀ¨ÊÖÐÔ¶þïÌú¹Ç¼ÜCpÅäÌ壨Chem. Eur. J. 2020, 26,14546£©£¬ÊÖÐÔ[2.2.2]ÇÅ»·CpÅäÌ壨Angew. Chem. Int. Ed. 2020, 59, 22436£©£¬ÒÔ¼°Æ½ÃæÊÖÐÔµÄCpRhIII´ß»¯¼Á£¨Angew. Chem. Int. Ed., 2022, DOI: 10.1002/anie.202201522£©£¬²¢ÀÖ³ÉÓ¦ÓÃÓÚ¶àÖÖ²î³Ø³ÆÌ¼Çâ»î»¯·´Ó³¡£¡£

³ýÁËCpRhIII´ß»¯£¬Íô¾ý¿ÎÌâ×éÔÚ·¼ÌþîÉ£¨ArRu£©´ß»¯µÄ²î³Ø³ÆÌ¼Çâ»î»¯·½ÃæÒ²È¡µÃÁËÖ÷ҪϣÍû¡£¡£ËûÃÇʹÓÃÊÖÐÔ˲̬µ¼Ïò»ùÕ½ÂÔÀÖ³ÉʵÏÖÁËîÉ(II)´ß»¯µÄ²î³Ø³Æ¶èÐÔC-H ¼ü»î»¯£¨Angew. Chem. Int. Ed. 2020, 59, 3475£©¡£¡£¿ËÈÕ£¬ËûÃÇÓÖ±¨µÀÁËÒ»Àà×ÔÖ÷Éè¼Æ¡¢¡¢¡¢½á¹¹ÐÂÓ±µÄ[2.2]¶Ô»··¬ÊÖÐÔ·¼ÌþÅäÌ壬²¢½«ÆäîÉ(II)ÂçºÏÎïÀÖ³ÉÓ¦ÓÃÓÚ²î³Ø³ÆÌ¼Çâ»î»¯·´Ó³£¬»ñµÃÁËÓÅÒìµÄÊÕÂÊÓë¶ÔӳѡÔñÐÔ£¨Í¼1£©¡£¡£ÖµµÃÒ»ÌáµÄÊÇ£¬¸ÃÑо¿ÊÇÊ×ÀýʹÓÃÊÖÐÔ·¼ÌþÅäÌå¿ØÖÆ¶ÔӳѡÔñÐÔµÄ²î³Ø³Æ´ß»¯Ì¼Çâ»î»¯¡£¡£¸ÃÑо¿Ð§¹û²»µ«¿ÉÒÔÏû³ýÈËÃǺã¾ÃÒÔÀ´¹ØÓÚÄÜ·ñʹÓÃÊÖÐÔ·¼ÌþÅäÌåʵÏÖîÉ´ß»¯²î³Ø³ÆÌ¼Çâ»î»¯µÄÒÉÂÇ£¬»¹Îª²î³Ø³ÆÌ¼Çâ»î»¯Ñо¿¿ª·¢ÁËз¾¶ºÍд߻¯¼ÁÀàÐÍ£¬¾ßÓÐÖ÷Òª¿ÆÑ§¼ÛÖµ¡£¡£

Ê×Ò³|ngµç×ÓÓÎÏ·Öйú¼¯ÍŹٷ½ÍøÕ¾

ͼ1. ÊÖÐÔ[2.2]¶Ô»··¬îÉ´ß»¯²î³Ø³ÆÌ¼Çâ»î»¯

¸ÃÑо¿Ð§¹û¿ËÈÕÒÔ¡°Chiral Arene Ligand as Stereocontroller for Asymmetric C-H Activation¡±ÎªÌâ½ÒÏþÓÚAngew. Chem. Int. Ed.£¬²¢±»ÆÀΪHot Paper¡£¡£ÂÛÎĵÚÒ»×÷ÕßÊÇngµç×ÓÓÎÏ·»¯Ñ§Ñ§Ôº2016¼¶±¾¿ÆÉúÁºê»£¬Í¨Ñ¶×÷ÕßΪngµç×ÓÓÎÏ·»¯Ñ§Ñ§ÔºÍô¾ý½ÌÊÚ¡£¡£¸ÃÑо¿ÊÂÇé»ñµÃÁ˹ú¼Ò×ÔÈ»¿ÆÑ§»ù½ðµÄ×ÊÖú£¨21971263£©¡£¡£

ÂÛÎÄÁ´½Ó£º£º£ºhttps://onlinelibrary.wiley.com/doi/10.1002/anie.202204926

¡¾ÍøÕ¾µØÍ¼¡¿