¿ËÈÕ£¬£¬ngµç×ÓÓÎÏ·»£»¯Ñ§Ñ§Ôº³²êͽÌÊÚÑо¿ÍŶӱ¨µÀÁËÒ»Àý»ùÓÚÒ¿(III)ÅäºÏÎïµÄθ°©ÕïÁÆÊÔ¼Á£¨FerriIridium£©¡£¡£FerriIridium¿É±»Ö×Áöϸ°ûÈÜøÌåµÄ²»ÎȹÌÌú³Ø£¨LIP£©ÌØÒìÐÔ¼¤»î£¬£¬ÌìÉú¼æ¾ß¿¹Ö×Áö»îÐÔÓëÁ׹ⷢ¹âµÄ´Î¼¶²úÆ·¡£¡£¾ÝÏàʶ£¬£¬ÕâÊÇÊ×ÀýFe(III)¼¤»îµÄÈÜøÌå°ÐÏòÒ¿(III)ǰҩÓÃÓÚθ°©ÕïÁÆ¡£¡£
Ö×Áö΢ÇéÐÎÓëÖ×ÁöÉú³¤¡¢¡¢ÃâÒßÌÓÒÝ¡¢¡¢ÄÍÒ©ÐÔ»ñµÃ¡¢¡¢Ö×ÁöÑ×Ö¢µÈϢϢÏà¹Ø£¬£¬Õë¶ÔÖ×Áö΢ÇéÐεÄʶ±ð̽Õë»ò¿¹Ö×ÁöǰҩµÄÑо¿£¬£¬ÌØÊâÊǶþÕߺÏÒ»µÄÕïÁÆÒ»Ì廯ÊÔ¼Á£¬£¬ÔÚÖ×ÁöÕï¶Ï¡¢¡¢¾«×¼ÖÎÁƵÈÁìÓò¾ßÓÐÁÉÀ«µÄÓ¦ÓÃÔ¶¾°¡£¡£
Ìúͨ³£±»ÒÔΪÊÇ·ÇÖ°©ÔªËØ¡£¡£½üÆÚµÄÑо¿Åú×¢£¬£¬Ö×ÁöµÄÐγɺÍÉú³¤Óëϸ°ûÖÐÌúµÄ¹ýÁ¿±£´æ¾ßÓÐÕýÏà¹ØÐÔ¡£¡£ÓÉÓÚÌúÓëϸ°ûÄÚµÄÑõ»¯Ñ»·¡¢¡¢×ÔÓÉ»ùÌìÉúÓÐ×ÅÇ×½üµÄÁªÏµ£¬£¬ÌúÎÈ̬ʧµ÷ÔÚ°©Ö¢µÈ¶àÖÖ¼²²¡Öб»·¢Ã÷¡£¡£¿ÉÊÇÕë¶ÔÖ×Áöϸ°û²»ÎȹÌÌú³Ø(LIP)µÄ¿¹Ö×ÁöÕïÁÆÒ»Ì廯ÊÔ¼ÁÏÖÔÚÉÐÏʼû±¨µÀ¡£¡£

ÓÃÓÚθ°©ÕïÁƵÄÒ¿(III)ÅäºÏÎï×÷ÓûúÀíʾÒâͼ
FerriIridium¶ÔÖ×Áöϸ°ûºÍÕý³£Ï¸°û¾ßÓиßÑ¡ÔñÐÔ¡£¡£µÍ¶¾µÄFerriIridiumͨ¹ý°ûÍÌ;¾¶±»Î¸°©Ï¸°ûÉãÈ¡ºó£¬£¬¶ù²è·Ó»ùÍÅÓëÈÜøÌåÖеÄÈý¼ÛÌúÀë×ÓòüºÏ²¢±»ÆäÑõ»¯±¬·¢ÖÐÐÄÌå¡£¡£ÔÚÈÜøÌåµÄËáÐÔÌõ¼þÏ£¬£¬ÖÐÐIJúÆ·½øÒ»²½Ë®½âÌìÉú¶Ô±½õ«À໯ºÏÎïºÍ¾ßÓÐÏßÁ£Ìå°ÐÏòÐÔµÄÅäºÏÎïIr-NH2¡£¡£¶Ô±½õ«À໯ºÏÎïºÍIr-NH2ͨ¹ý×ÌÈÅϸ°ûºôÎüÁ´¡¢¡¢±¬·¢ÑÄÐÔÑõÎïÖÊʵÏÖÐͬ¿¹Ö×ÁöЧ¹û¡£¡£Á¬ÐøÁ½ÖܵĸøÒ©ºó£¬£¬FerriIridiumÔÚÂãÊóÖ×ÁöÄ£×ÓÖÐÌåÏÖ³öÁ˺ÜÊÇÓÅÒìµÄ¿¹Ö×Áö»îÐÔ¡£¡£±ðµÄ£¬£¬Ê¹ÓÃIr-NH2µÄÇ¿Á׹ⷢÉ䣬£¬ÔÚϸ°ûÌõÀíºÍÂãÊóÖ×ÁöÄ£×ÓÖоùʵÏÖÁ˹ØÓÚθ°©Ï¸°ûµÄʶ±ð¡£¡£
¸ÃÑо¿Ð§¹û½ÒÏþÔÚ»¯Ñ§×ÛºÏÆÚ¿¯Angewandte Chemie International Edition £¬£¬²¢±»ÆÀΪVIPÂÛÎÄ¡£¡£ÎÄÕµĵÚÒ»×÷ÕßÊÇngµç×ÓÓÎÏ·»¯Ñ§Ñ§Ôº²©Ê¿Ñо¿Éú¿õʵ£¬£¬Í¨Ñ¶×÷ÕßΪ³ÂÓí¸±½ÌÊںͳ²êͽÌÊÚ£¨Shi Kuang, Xinxing Liao, Xianrui Zhang, Thomas W. Rees, Ruilin Guan, Kai Xiong, Yu Chen*, Liangnian Ji, Hui Chao*, Angew. Chem. Int. Ed., 2020, 59, 3315-3321£©¡£¡£ÒÔÉÏÑо¿ÊÂÇé»ñµÃÁ˹ú¼Ò×ÔÈ»¿ÆÑ§»ù½ð£¨21525105, 21778079£©£¬£¬973ÏîÄ¿£¨2015CB856301£©£¬£¬½ÌÓý²¿ £¨No. IRT-17R111£©ºÍ¹ãÖÝ¡°Ö齿Ƽ¼ÐÂÐÇ¡±ÍýÏë £¨201806010136£©µÈÏîÄ¿µÄ×ÊÖú¡£¡£
ÂÛÎÄÁ´½Ó£º£º£ºhttps://doi.org/10.1002/anie.201915828